Struggling Liverpool will seek to take revenge of their 1-4 defeat to Napoli in the UEFA Champions League on Tuesday.
The Reds will host the Serie A club at Anfield stadium for the 22:00 kick-off.
Napoli crushed Liverpool 4-1 in the opening game of the UEFA Champions League's group stage.
The Premier League side retuned to the winning ways in gameweek two after snatching a 2-1 win over Ajax, before pulling off their second win in a row after defeating Rangers 2-0.
Jurgen Klopp's men thrashed Rangers in gameweek four 7-1 in a game, which saw Egyptian star Mohamed Salah scoring the fastest hat-trick in the history of the competition. They secured their fourth win in a row after beating Ajax 3-0.
On the other hand, the Italian clubs kicked off their adventure by a 4-1 win over Liverpool, followed by a 3-0 victory over Rangers, before crushing Ajax 6-1 in gameweek three.
They managed to maintain their 100% start of the UEFA Champions League by defeating Ajax 4-2 in gameweek four, before securing their fifth consecutive win over Rangers in matchweek five.